全文获取类型
收费全文 | 2879篇 |
免费 | 354篇 |
国内免费 | 348篇 |
专业分类
化学 | 780篇 |
晶体学 | 23篇 |
力学 | 330篇 |
综合类 | 82篇 |
数学 | 1233篇 |
物理学 | 1133篇 |
出版年
2024年 | 4篇 |
2023年 | 28篇 |
2022年 | 36篇 |
2021年 | 71篇 |
2020年 | 65篇 |
2019年 | 67篇 |
2018年 | 69篇 |
2017年 | 97篇 |
2016年 | 100篇 |
2015年 | 99篇 |
2014年 | 177篇 |
2013年 | 227篇 |
2012年 | 182篇 |
2011年 | 193篇 |
2010年 | 141篇 |
2009年 | 190篇 |
2008年 | 203篇 |
2007年 | 197篇 |
2006年 | 161篇 |
2005年 | 163篇 |
2004年 | 135篇 |
2003年 | 118篇 |
2002年 | 114篇 |
2001年 | 94篇 |
2000年 | 78篇 |
1999年 | 86篇 |
1998年 | 64篇 |
1997年 | 71篇 |
1996年 | 51篇 |
1995年 | 34篇 |
1994年 | 36篇 |
1993年 | 19篇 |
1992年 | 29篇 |
1991年 | 16篇 |
1990年 | 15篇 |
1989年 | 7篇 |
1988年 | 20篇 |
1987年 | 7篇 |
1986年 | 14篇 |
1985年 | 9篇 |
1984年 | 13篇 |
1983年 | 7篇 |
1982年 | 10篇 |
1981年 | 11篇 |
1979年 | 7篇 |
1978年 | 7篇 |
1977年 | 8篇 |
1974年 | 5篇 |
1973年 | 5篇 |
1972年 | 7篇 |
排序方式: 共有3581条查询结果,搜索用时 171 毫秒
11.
Mathieu Boiret Anna de Juan Nathalie Gorretta Yves-Michel Ginot Jean-Michel Roger 《Analytica chimica acta》2015
Raman chemical imaging provides chemical and spatial information about pharmaceutical drug product. By using resolution methods on acquired spectra, the objective is to calculate pure spectra and distribution maps of image compounds. With multivariate curve resolution-alternating least squares, constraints are used to improve the performance of the resolution and to decrease the ambiguity linked to the final solution. Non negativity and spatial local rank constraints have been identified as the most powerful constraints to be used. 相似文献
12.
Previously, master equation (ME) simulations using semiclassical transition state theory (SCTST) and high-accuracy extrapolated ab initio thermochemistry (HEAT) predicted rate constants in excellent agreement with published experimental data over a wide range of pressure and temperatures ≳250 K, but the agreement was not as good at lower temperatures. Possible reasons for this reduced performance are investigated by (a) critically evaluating the published experimental data and by investigating; (b) three distinct ME treatments of angular momentum, including one that is exact at the zero- and infinite-pressure limits; (c) a hindered-rotor model for HOCO that implicitly includes the cis- and trans-conformers; (d) possible empirical adjustments of the thermochemistry; (e) possible empirical adjustments to an imaginary frequency controlling tunneling; (f) including or neglecting the prereaction complex PRC1; and (g) its possible bimolecular reactions. Improvements include better approximations to factors in SCTST and using the Hill and van Vleck treatment of angular momentum coupling. Evaluation of literature data does not reveal any specific shortcomings, but the stated uncertainties may be underestimated. All ME treatments give excellent fits to experimental data at T ≥ 250 K, but the discrepancy at T < 250 K persists. Note that each ME model requires individual empirical energy transfer parameters. Thermochemical adjustments were unable to match the experimental H/D kinetic isotope effects. Adjusting an imaginary frequency can achieve good fits, but the adjustments are unacceptably large. Whether PRC1 and its possible bimolecular reactions are included had little effect. We conclude that none of the adjustments is an improvement over the unadjusted theory. Note that only one set of experimental data exists in the regime of the discrepancy with theory, and data for DO + CO are scanty. 相似文献
13.
14.
This paper will deal with an anisotropic area-preserving flow which keeps the convexity of the evolving curve and the limiting curve converges to a homothety of a symmetric smooth strictly convex plane curve. 相似文献
15.
In order to determine an appropriate amount of premium, statistical goodness-of-fit criteria must be supplemented with actuarial ones when assessing performance of a given candidate pure premium. In this paper, concentration curves and Lorenz curves are shown to provide actuaries with effective tools to evaluate whether a premium is appropriate or to compare two competing alternatives. The idea is to compare the premium income for sub-portfolios gathering low risks (identified as low by means of the premiums under consideration) to the true one, or equivalently, to the actual losses. Numerical illustrations performed on hypothetical data and real ones demonstrate the usefulness of the proposed approach. 相似文献
16.
《Operations Research Letters》2020,48(4):460-466
Area under ROC curve (AUC) is a performance measure for classification models. We propose new distributionally robust AUC models (DR-AUC) that rely on the Kantorovich metric and approximate AUC with the hinge loss function, and derive convex reformulations using duality. The DR-AUC models outperform deterministic AUC and support vector machine models and have superior worst-case out-of-sample performance, thereby showing their robustness. The results are encouraging since the numerical experiments are conducted with small-size training sets conducive to low out-of-sample performance. 相似文献
17.
非均质复合材料的宏观力学性能往往取决于细观组分的分布方式和力学性能,但是建立明确的关系表达式极其困难。为了应对这一挑战,以混凝土为研究对象,提出了一种基于深度学习的策略,能够高效、准确地通过细观模型图像信息获取应力-应变曲线。首先,使用基于卷积神经网络(convolutional neural network,CNN)的GoogLeNet模型进行图像信息识别和提取,并针对应力-应变曲线的复杂性特点,进行了数据预处理操作,并且设计了相应的多任务损失函数。数据集中的细观模型图像采用基于Monte-Carlo的随机骨料模型生成,并且使用数值模拟试验获取对应细观模型的单轴压缩应力-应变曲线。最后,通过对神经网络的训练和测试评估了所提出方法的可行性。结果表明,GoogLeNet模型训练效率和预测精度均优于AlexNet和ResNet模型,具有良好的泛化能力和鲁棒性。 相似文献
18.
In the present paper, we investigate the blow-up dynamics for local solutions to the semilinear generalized Tricomi equation with combined nonlinearity. As a result, we enlarge the blow-up region in comparison to the ones for the corresponding semilinear models with either power nonlinearity or nonlinearity of derivative type. Our approach is based on an iteration argument to establish lower bound estimates for the space average of local solutions. Finally, we obtain upper bound estimates for the lifespan of local solutions as byproduct of our iteration argument. 相似文献
19.
《Mathematische Nachrichten》2017,290(16):2560-2566
In this paper, we describe a second main theorem of holomorphic curves in , of hyper‐order strictly less than 1, that involves a general linear operator . As an application, we derive a truncated second main theorem of degenerate holomorphic curves of hyper‐order strictly less than 1 using Nochka weights. 相似文献
20.